Search results for "enzymatic degradation"

showing 2 items of 2 documents

Facile and efficient chemical functionalization of aliphatic polyesters by cross metathesis

2016

International audience; An effective preparation of new tailor-made macromolecular materials via a combination of two (atom-efficient) catalytic transformations is reported. First, new aliphatic polyesters with alternated composition have been prepared using a salen aluminum catalyst system. Next, the pendant vinyl moieties in those copolymers have been selectively transformed into various functional groups by metathesis in the presence of homogeneous Grubbs catalysts. The latter metathesis reaction has been optimized in terms of catalytic activity and selectivity, to define the conditions for an effective and safe procedure that does not affect the macromolecular architecture. All polymer …

plga microspheresphosphate-buffered solutionin-vivo degradationPolymers and PlasticsBioengineeringmolecular-weight poly(l-lactide)010402 general chemistryMetathesis01 natural sciencesBiochemistry[ CHIM ] Chemical SciencesCatalysisacid) microspheresCopolymerSalt metathesis reactionenzymatic degradation[CHIM]Chemical SciencesOrganic chemistryRing-opening metathesis polymerisationcyclic anhydrides010405 organic chemistryChemistryring-opening copolymerizationOrganic Chemistryrenewable resources0104 chemical sciencesPolyester[ CHIM.POLY ] Chemical Sciences/Polymers[CHIM.POLY]Chemical Sciences/Polymersbiodegradable polymersSelectivityAcyclic diene metathesis
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Isolation of Central Nervous System (CNS) Infiltrating Cells

2014

Leukocyte infiltration of the central nervous system (CNS) occurs under certain pathogenic conditions and most often results in severe disorders. Therefore, the isolation and analysis of such infiltrating cell populations is necessary for elucidating the underlying pathogenic mechanisms. Here we describe a simple and straightforward protocol for cell isolation from the inflamed CNS, which combines mechanical dissociation and enzymatic degradation of the tissue. Additionally, purification by Percoll gradient centrifugation provides a great yield of the infiltrating material. The isolated cells can be further used for downstream applications such as cell sorting, cellular or molecular analysi…

medicine.anatomical_structureChemistryCellCentral nervous systemmedicinePercoll gradient centrifugationCell isolationCell sortingmedicine.diseaseInfiltration (medical)Molecular analysisCell biologyEnzymatic degradation
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